Oxidation Tutorial

August 7, 2024·Devraj Bagchi
Devraj Bagchi
Oxidation Oxidation Reaction Carboxylic Acid Ketone Harsh

General Scheme of the Pinnick Oxidation

The Pinnick Oxidation is an economical and gentle method to oxidize aldehydes to carboxylic acids.1

Summary

The reaction entry summary. Find the general scheme and full summarized mechanisms here.

General Scheme

This section briefly summarizes what can and cannot undergo reactions.

  • Aldehydes are oxidized to Carboxylic Acids.
  • The hypochlorous acid by-product is scavenged.

General Mechanism

This section briefly summarizes steps to find the product and perform the mechanisms.

Quick steps to finding the product

  1. Identify the reagents.
  2. Identify the product which needs to be formed.
  3. Form the HO-Cl reagent needed to form the Carboxylic Acid.
  4. React the Aldehyde with HO-Cl and form the Carboxylic Acid product.
  5. Scavenge the HO-Cl by-product.
Full Aldehyde to Carboxylic Acid Mechanism
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Always remember to repeatedly practice your mechanisms and getting your reagents correct. Take advantage of our materials and/or keep practicing on a whiteboard or paper until you get it right every single time.
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